Characterizing Atmospheric Brown Carbon and Its Emission Sources during Wintertime in Shanghai, China

نویسندگان

چکیده

Atmospheric brown carbon (BrC) is a kind of organic aerosol that efficiently absorbs ultraviolet-visible light and has an impact on climate forcing. We conducted in-depth field study ambient aerosols at monitoring point in Shanghai, China, aiming to investigate the potential emission sources, molecular structures, contributions absorptions BrC chromophores. The results indicated nine molecules were identified as nitroaromatic compounds, five which (4-nitrophenol, 4-nitrocatechol, 2-nitro-1-naphthol, 3-methyl-4-nitrocatechol, 2-methyl-4-nitrophenol) usually came from biomass burning or produced photo-oxidation anthropogenic volatile compounds (e.g., toluene, benzene) under high-NOx conditions. 4-nitrophenol was strongest chromophore accounted for 13% total absorption λ = 365 nm. estimated black approximately three times value methanol-soluble ratios K+/OC K+/EC, correlations with WSOC, OC, HULIS-C K+, MAE values methanol extracts also primary emissions contributed more compared secondary formation during wintertime Shanghai. Therefore, control still most urgent strategy reducing

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ژورنال

عنوان ژورنال: Atmosphere

سال: 2022

ISSN: ['2073-4433']

DOI: https://doi.org/10.3390/atmos13060991